Volume 289
Main Index

Issue 1, Pages 1-230 (2 July 1985)

Base promoted rearrangements of cyclopentadienylacyl- and -carboxyalkyl-metal complexes Pages c13-c17 Steven Abbott, Gordon J. Baird, Stephen G. Davies, Isabelle M. Dordor-Hedgecock, Timothy R. Maberly, Jonathan C. Walker, Peter Warner

Orbital Interactions in Chemistry : By T.A. Albright, J.K. Burdett and M.H. Whangbo. Published by John Wiley and Sons, New York 1985, £63.25. ISBN 0 471873934, 447 pages. Pages c18-c19 D. M. P. Mingos

Heterobimetallic (Pd/Pt---Ge/Sn) trinuclear clusters containing a planar M3(CO)3(μ2-M′)3 core: Spectroscopy, cyclic voltammetry, and ESR characterisation of electrochemical reduction products. Crystal structures of [(M{μ2-Sn(NR2)2}(CO))3] (M = Pd or Pt, R = SiMe3) Pages c1-c4 Graeme K. Campbell, Peter B. Hitchcock, Michael F. Lappert, Mohan C. Misra

Synthese und kristallstruktur von heterometallzweikernkomplexen mit vinyliden-brückenliganden Pages c5-c12 H. Werner, F. J. Garcia Alonso, H. Otto, K. Peters and, H. G. Von Schnering

Author index Page c20

Gemischte organozinkverbindungen durch austauschreaktionen von diorganozinkverbindungen Pages 1-8 Hans Nehl, Walter R. Scheidt

Bis(α,β-ditrifloxystyryl)mercury: Synthesis and crystal structure Pages 9-16 Gerhard Maas, Ralf Brückmann, Wolfgang Lorenz

Electrochemical symmetrization of carboranylmercury salts Pages 17-21 A. Ya. Usiatinsky, V. A. Shreider, T. M. Shcherbina, V. I. Bregadze, N. N. Godovikov, I. L. Knuniants

Contributions to group IV organometallic chemistry : VIII. Preparation and properties of some organo-1,3,2-dioxasilacycloheptanes and their cyclic dimers Pages 23-44 R. Harry Cragg, Rob D. Lane

Diorganosilacyclopent-3-ene derivatives from diorganodichlorosilanes and butadienemagnesium: Evidence for crotyl-Grignard intermediates Pages 45-49 Wolf Juergen Richter

Relative stabilities of 1,4-disilabenzene and its valence isomers Pages 51-55 Jayaraman Chandrasekhar, Paul von Rague Schleyer

Übergangsmetallkomplexe mit schwefelliganden : X. Substitutions- und redox-reaktionen von molybdän(0)-carbonyl-komplexen mit den mehrzähnigen thioetherthiol-liganden 1,2-methylthiobenzolthiol, 1,4,7-trithiaheptan, 23,8,9-dibenzo-1,4,7,10-tetrathiadecan sowie 1,2-benzoldithiol Pages 57-69 Dieter Sellmann, Lothar Zapf

Übergangsmetallkomplexe mit schwefelliganden : XII. Die alkylierungvon molybdän-1,2-benzoldithiolato-komplexen in abhängigkeit von der Mo-oxidationsstufe; synthese von molybdän-nitrosyl-komplexen des typs [Mo(NO)2S4] sowie [Mo(NO)S6] (Sx = mehrzähniger organoschwefelligand) Pages 71-79 Dieter Sellmann, Lothar Zapf, Johannes Keller, Matthias Moll

Photochemical and thermal behaviour of isocyanide complexes : III. Photochemistry of Fe(bipy)(CNCH3)4(BF4)2 and Fe(bipy)(CNCH3)2(C4H10N4)(BF4)2 in acetonitrile Pages 81-90 L. L. Costanzo, S. Giuffrida, G. De Guidi, V. Cucinotta, G. Condorelli

Syntheses of ferrocenophanes containing aromatic or heteroaromatic rings in the bridging chain Pages 91-95 Masaru Sato, Shinsuke Tanaka, Seiji Ebine and, Kenichi Morinaga, Sadatoshi Akabori

Activity of ruthenium/iodine catalysts for the carbonylation of esters to give carboxylic acids Pages 97-106 Mathias Lütgendorf, Edel O. Elvevoll, Michael Röper

Homologation with CO + H2 of ethyl orthoformate in the presence of ruthenium catalysts: A stepwise hydrogenation and carbonylation reaction Pages 107-116 G. Braca, A. M. Raspolli Galletti, G. Sbrana, R. Lazzaroni

Indenyl complexes of ruthenium(II). Crystal structure of [Ru(CO)(PPh3)2(η5-C9H7)]ClO4·CH2Cl2 Pages 117-131 Luis A. Oro, Miguel A. Ciriano, Marina Campo, Concepcion Foces-Foces and, Felix H. Cano

Permethylmetallocene : V. Reaktionen des decamethylruthenicenium-kations Pages 133-139 V. Kölle, J. Grub

Basische metalle : LII. Synthese von carbenoid- und ylidcobalt(III)-komplexen aus substitutionslabilen cobalt(I)-vorstufen Pages 141-155 L. Hofmann, H. Werner

Cyclic voltammetry of silyl- and stannyl-tricobalt cluster compounds Pages 157-162 Alan M. Bonny, Thomas J. Crane, Noel A.P. Kane-Maguire

Homolytic displacement at carbon : XI. Intramolecular homolytic displacement as a route to cyclopentane and tetrahydrofuran derivatives from hex-5-enyl- andhex-3-oxo-5-enylcobaloximes Pages 163-171 Christophe Bongars, Peter Bougeard, Adrian Bury, Christopher J. Cooksey, Michael D. Johnson, Stewart Mitchell, Paul A. Owens, Famida Rajah

Synthesis and reactions of a nucleophilic bis(μ-dimethylphosphido)dicobalt complex. The crystal and molecular structure of [C5H5Co(μ-PMe2)]2 and [(C5H5Co)2(μ-H)(μ-PMe2)2]BPh4 Pages 173-188 H. Werner, W. Hofmann, R. Zolk, L. F. Dahl, J. Kocal, A. Kühn

Thermal decomposition of η5-cyclopentadienyl-η2-propenealkylnickel complexes Pages 189-200 S. Pasynkiewicz, H. Lehmkuhl

Synthese und reaktionsverhalten asymmetrischer metallacyclen des palladiums und platins Pages 201-213 Hans-Peter Abicht, Kurt Issleib

Decarboxylierung cyclischer und acyclischer dicarboxylato-komplexe des platins Pages 215-222 O. J. Scherer, K. Hussong, G. Wolmershäuser

Addition conjuguée régiospécifique et sélective sur les α,β-énones et -énals d'une chaîne -acétylénique (r) á l'aide des trialkylmagnésiocuprates mixtes (t-Bu)2(R)CuLiMgCl et (Me3SiCC)(R2)Cu(MgCl)2 Pages 223-230 J. Drouin, G. Rousseau

Issues 2-3, Pages 231-448 (9 July 1985)

Subject index Pages c29-c34

Spontane bildung von selenobenzaldehyde-verbrückten zweikernkomplexen [(CO)5W]2(μ2,η2-Se=C(H)C6H4R) aus (CO)5W[Se=C(H)C6H4R] Pages c21-c25 Helmut Fischer, Siegfried Zeuner, Helmut Guido Alt

Author index Pages c27-c28

Errata Page c26

Errata Page c26

Pyrolysis of silicon-containing cyclic polysulphides Pages 231-237 E. A. Chernyshev, O. V. Kuz'min, A. V. Lebedev, V. G. Zaikin and, A. I. Mikaya

Reactivite comparee des isomeres imine et enamine silicies: Synthese enantioselective de l'(oxo-2 cyclohexyl)-3 propionate de methyle Pages 239-246 Michel Fourtinon, Bernard De Jeso, Jean-Claude Pommier

Hydrido-silyl-komplexe : VI. Elektronische und sterische einflüsse von phosphin-liganden auf die aktivierungs-parameter der reduktiven eliminierung von diphenylsilan aus (η5-CH3C5H4)(CO)(PR3)Mn(H)SiHPh2-komplexen Pages 247-256 G. Kraft, C. Kalbas, U. Schubert

Vinylketene : VI. [2+ 2]cycloaddition an silylvinylketene: Konkurrierende addition von inaminen an die keten-C=C- und die keten-C=O-bindung Pages 257-262 Karl Heinz Dötz, Jochen Mühlemeier, Barbara Trenkle

The electronic structure of η5-pentamethylcyclopentadienyl complexes of group IV elements from He(I) and He(II) photoelectron spectroscopy Pages 263-270 Giovanni Bruno, Enrico Ciliberto, Ignazio L. Fragalà, Peter Jutzi

Organotin biocides : V. The structure of dicyclohexyltin dichloride Pages 271-279 K. C. Molloy, K. Quill, I. W. Nowell

Some structural chemistry of organolead(IV) compounds containing lead—sulphur bonds. The crystal and molecular structures of triphenyllead benzenethiolate, Ph3PbSPh, triphenyllead O,O′-diethyldithiophosphate, Ph3PbS2P(OEt)2, and diphenyllead bis(O,O′-dibenzyldithiophosphate), Ph2Pb[S2P(OCH2Ph)2]2 Pages 281-293 Michael G. Begley, Christine Gaffney, Philip G. Harrison, Andrew Steel

Gehinderte ligandbewegungen in übergangsmetallkomplexen : XXV. Synthese und dynamisches verhalten von dicarbonyl(η4-dien)-1,2-bis(dimethylphosphino)ethan-chrom(0) Pages 295-308 Cornelius G. Kreiter, Michael Kotzian

Hydroboration d'amines insaturees : IX. Role d'une liaison PIV-N sur la complexation azote—bore lors de la reaction d'hydroboration d'amines N-allyliques Pages 309-317 Zahra Benmaarouf-Khallaayoun, Michel Baboulene, Vincent Speziale, Armand Lattes

Synthesis and structure of dimeric metallocene derivatives of transition metals of groups IV and V. Crystal and molecular structures of (η5:η5-C10H8)(C5H5)2Nb2(μ-H)(μ-OEt) and (η5:η5-C10H8)(C5H5)2Ti2(μ-H)(μ-Cl) Pages 319-329 E. G. Perevalova, I. F. Urazowski, D. A. Lemenovskii, Yu. L. Slovokhotov and, Yu. T. Struchkov

Titanium-catalyzed Diels-Alder cycloaddition of conjugated dienes to bis(trimethylsilyl)acetylene. 1,2-bis(trimethylsilyl)cyclohexa-1,4-diene, 1,2-bis(trimethylsilyl)benzene, and their methyl derivatives Pages 331-339 K. Mach, H. Antropiusová, L. Petrusová, F. Tureek, V. Hanu, P. Sedmera, J. Schraml

Perfluormethyl-element-liganden : XXXIII. 1,3,2-dithiaphospholane R und R (R = CH3, CF3) als liganden in Cr(CO)x-komplexen (x = 4, 5) Pages 341-355 J. Grobe, D. Le Van, J. Szameitat

Valenztautomerie an stibiniden-komplexen. Synthese von stiban und distiben-komplexen Pages 357-366 Ute Weber, Gottfried Huttner, Olaf Scheidsteger, Laszlo Zsolnai

Carbon—carbon bond formation in reactions between tolylmethylidyne(dicarbonyl)(cyclopentadienyl)tungsten and organo-chromium or -zinc compounds Pages 367-376 John C. Jeffery, Andrew L. Ratermann, F. Gordon A. Stone

Molecular structure of trans-bis[1,2-bis(diphenylphosphino)-ethane]chloro (t-butylisocyanide)rhenium(I)-tetrahydrofuran solvate, trans-{ReCl[CN(t-C4H9]-(Ph2PCH2CH2PPh2)2} · C4H8O Pages 377-383 Maria A. A. F. De C.T. Carrondo, Angela M. T. S. Domingos, G. A. Jeffrey

Methanol as a hydrogen donor in reactions homogeneously catalysed by ruthenium and rhodium complexes Pages 385-395 Thomas A. Smith, Peter M. Maitlis

Oxidative addition reactions to (C5H4CH3)Co(CO)2 and preparation of the mono-μ-hydrido complexes [(C5H4CH3)CoX]2(μ-H)(μ-X) (X = Cl, Br, I) Pages 397-402 S. Delgado, J. Macazaga, C. Moreno, J. R. Masaguer

Homolytic displacement at carbon : X. Toluenesulphonyl iodide as a source of toluenesulphonyl radicals for the formation of allyl-, benzyl-, cyclopropylcarbinyl-, spirocyclopropylcycloalkyl-, bicyclo[1.0.3]alkyl-, and bicyclo[1.0.4]Alkyl-4-tolylsulphones from organocobaloximes Pages 403-415 Martyn R. Ashcroft, Peter Bougeard, Adrian Bury, Christopher J. Cooksey, Michael D. Johnson

A UV photoelectronic spectroscopic study of the electronic structures of some cobalt and rhodium “half sandwich” complexes Pages 417-424 C. Cauletti, C. Furlani, C. Puliti, H. Werner

Formation and reactivity of palladium hydride complexes, [(PPh3)3PdH]+ and [(PPh3)2Pd(μ-H)(μ-CO)Pd(PPh3)2]+, in aqueous trifluoroacetic acid solutions Pages 425-430 V. N. Zudin, V. D. Chinakov, V. M. Nekipelov, V. A. Likholobov, Yu. I. Yermakov

Variable pressure and temperature 1H NMR studies on exchange mechanisms in π-allylpalladium(II) complexes Pages 431-438 Ron L. Batstone-Cunningham, Harold W. Dodgen, John P. Hunt, D. Max Roundhill

Palladium and platinum complexes of α-ketoesters. Crystal structure of trans-[Pt{P(C6H11)3}2(H){OO}] Pages 439-448 A. Grassi, P. Longo, A. Musco, W. Porzio, A. Scrivanti